Rapid probe of the nicotine spectra by high-resolution rotational spectroscopy

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dc.identifier.uri http://dx.doi.org/10.15488/2198
dc.identifier.uri http://www.repo.uni-hannover.de/handle/123456789/2223
dc.contributor.author Grabow, Jens-Uwe
dc.contributor.author Mata, S.
dc.contributor.author Alonso, J.L.
dc.contributor.author Peña, I.
dc.contributor.author Blanco, S.
dc.contributor.author López, J.C.
dc.contributor.author Cabezas, C.
dc.date.accessioned 2017-11-01T09:44:44Z
dc.date.available 2017-11-01T09:44:44Z
dc.date.issued 2011
dc.identifier.citation Grabow, J.-U.; Mata, S.; Alonso, J.L.; Peña, I.; Blanco, S. et al.: Rapid probe of the nicotine spectra by high-resolution rotational spectroscopy. In: Physical Chemistry Chemical Physics 13 (2011), Nr. 47, S. 21063-21069. DOI: https://doi.org/10.1039/c1cp22197c
dc.description.abstract Nicotine has been investigated in the gas phase and two conformational forms were characterized through their rotational spectra. Two spectroscopic techniques have been used to obtain the spectra: a new design of broadband Fourier transform microwave (FTMW) spectroscopy with an in-phase/quadrature- phase-modulation passage-acquired-coherence technique (IMPACT) and narrowband FTMW spectroscopy with coaxially oriented beam-resonator arrangement (COBRA). The rotational, centrifugal distortion and hyperfine quadrupole coupling constants of two conformers of nicotine have been determined and found to be in N-methyl trans configurations with the pyridine and pyrrolidine rings perpendicular to one another. The quadrupole hyperfine structure originated by two 14N nuclei has been completely resolved for both conformers and used for their unambiguous identification. © 2011 the Owner Societies. eng
dc.language.iso eng
dc.publisher Cambridge : Royal Society of Chemistry
dc.relation.ispartofseries Physical Chemistry Chemical Physics 13 (2011), Nr. 47
dc.rights Es gilt deutsches Urheberrecht. Das Dokument darf zum eigenen Gebrauch kostenfrei genutzt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden. Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
dc.subject nicotine eng
dc.subject nitrogen eng
dc.subject pyridine eng
dc.subject pyridine derivative eng
dc.subject pyrrolidine eng
dc.subject pyrrolidine derivative eng
dc.subject article eng
dc.subject chemistry eng
dc.subject Fourier analysis eng
dc.subject gas eng
dc.subject infrared spectrophotometry eng
dc.subject quantum theory eng
dc.subject Fourier Analysis eng
dc.subject Gases eng
dc.subject Nicotine eng
dc.subject Nitrogen eng
dc.subject Pyridines eng
dc.subject Pyrrolidines eng
dc.subject Quantum Theory eng
dc.subject Spectrophotometry, Infrared eng
dc.subject.ddc 540 | Chemie ger
dc.title Rapid probe of the nicotine spectra by high-resolution rotational spectroscopy
dc.type Article
dc.type Text
dc.relation.issn 1463-9076
dc.relation.doi https://doi.org/10.1039/c1cp22197c
dc.bibliographicCitation.issue 47
dc.bibliographicCitation.volume 13
dc.bibliographicCitation.firstPage 21063
dc.bibliographicCitation.lastPage 21069
dc.description.version publishedVersion
tib.accessRights frei zug�nglich


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