dc.identifier.uri |
http://dx.doi.org/10.15488/1805 |
|
dc.identifier.uri |
http://www.repo.uni-hannover.de/handle/123456789/1830 |
|
dc.contributor.author |
Wang, Liang-Liang
|
|
dc.contributor.author |
Kirschning, Andreas
|
|
dc.date.accessioned |
2017-08-30T11:46:24Z |
|
dc.date.available |
2017-08-30T11:46:24Z |
|
dc.date.issued |
2017 |
|
dc.identifier.citation |
Wang, L.-L.; Kirschning, A.: Total synthesis of elansolids B1 and B2. In: Beilstein Journal of Organic Chemistry 13 (2017), S. 1280-1287. DOI: https://doi.org/10.3762/bjoc.13.124 |
|
dc.description.abstract |
The elansolids A1–A3, B1, and B2 are secondary metabolites formed by the gliding bacterium Chitinophaga sancti. They show antibacterial activity against Gram-positive bacteria. A second generation total synthesis of the antibiotic elansolid B1 (2) and the first synthesis of elansolid B2 (3) are reported. In contrast to previous work, the (Z,E,Z)-triene at C10–C15 was assembled by using an optimized C–C cross-coupling sequence with a Suzuki cross-coupling reaction as key step. |
eng |
dc.language.iso |
eng |
|
dc.publisher |
Frankfurt am Main : Beilstein-Institut zur Förderung der Chemischen Wissenschaften |
|
dc.relation.ispartofseries |
Beilstein Journal of Organic Chemistry 13 (2017) |
|
dc.rights |
CC BY 4.0 Unported |
|
dc.rights.uri |
https://creativecommons.org/licenses/by/4.0/ |
|
dc.subject |
Antibiotics |
eng |
dc.subject |
Polyenes |
eng |
dc.subject |
Polyketides |
eng |
dc.subject |
Stille reaction |
eng |
dc.subject |
Suzuki reaction |
eng |
dc.subject |
Total synthesis |
eng |
dc.subject.ddc |
540 | Chemie
|
ger |
dc.title |
Total synthesis of elansolids B1 and B2 |
eng |
dc.type |
Article |
|
dc.type |
Text |
|
dc.relation.issn |
1860-5397 |
|
dc.relation.doi |
https://doi.org/10.3762/bjoc.13.124 |
|
dc.bibliographicCitation.volume |
13 |
|
dc.bibliographicCitation.firstPage |
1280 |
|
dc.bibliographicCitation.lastPage |
1287 |
|
dc.description.version |
publishedVersion |
|
tib.accessRights |
frei zug�nglich |
|