dc.identifier.uri |
http://dx.doi.org/10.15488/155 |
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dc.identifier.uri |
http://www.repo.uni-hannover.de/handle/123456789/177 |
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dc.contributor.author |
Cox, Russell J.
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dc.contributor.author |
Szwalbe, Agnieszka J.
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dc.contributor.author |
Williams, Katherine
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dc.contributor.author |
O'Flynn, Daniel E.
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dc.contributor.author |
Bailey, Andrew M.
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dc.contributor.author |
Mulholland, Nicholas P.
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dc.contributor.author |
Vincent, Jason L.
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dc.contributor.author |
Willis, Christine L.
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dc.contributor.author |
Simpson, Thomas J.
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dc.date.accessioned |
2016-01-12T11:57:03Z |
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dc.date.available |
2016-10-02T22:05:23Z |
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dc.date.issued |
2015-10-02 |
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dc.identifier.citation |
Szwalbe, Agnieszka J.; Williams, Katherine; O'Flynn, Daniel E.; Bailey, Andrew M.; Mulholland, Nicholas P.; Vincent, Jason L.; Willis, Christine L.; Cox, Russell J.; Simpson, Thomas J.: Novel nonadride, heptadride and maleic acid metabolites from the byssochlamic acid producer Byssochlamys fulva IMI 40021 – an insight into the biosynthesis of maleidrides. In: Chemical Communications 51 (2015), Nr. 96, S. 17088-17091. DOI: http://dx.doi.org/10.1039/C5CC06988B |
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dc.description.abstract |
The filamentous fungus Byssochlamys fulva strain IMI 40021 produces (+)-byssochlamic acid 1, its novel dihydroanalogue 2 and four related secondarymetabolites. Agnestadrides A, 17 and B, 18 constitute a novel class of seven-membered ring, maleic anhydride-containing (hence termed heptadride) natural products. The putative maleic anhydride precursor 5 for both nonadride and heptadride biosynthesis was isolated as a fermentation product for the first time and its structure confirmed by synthesis. Acid 5 undergoes facile decarboxylation to anhydride 6. The generic term maleidrides is proposed to encompass biosynthetically-related compounds containing maleic anhydride moieties fused to an alicyclic ring, varying in size and substituents. |
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dc.language.iso |
eng |
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dc.publisher |
Cambridge : Royal Society of Chemistry |
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dc.relation.ispartofseries |
Chemical Communications (2015) |
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dc.rights |
CC BY 3.0 Unported |
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dc.rights.uri |
https://creativecommons.org/licenses/by/3.0/ |
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dc.subject |
Byssochlamys fulva |
eng |
dc.subject |
Pilz |
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dc.subject |
Byssochlamys fulva |
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dc.subject.classification |
Byssochlamys fulva |
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dc.subject.ddc |
540 | Chemie
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dc.title |
Novel nonadride, heptadride and maleic acid metabolites from the byssochlamic acid producer Byssochlamys fulva IMI 40021 – an insight into the biosynthesis of maleidrides |
eng |
dc.type |
Article |
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dc.type |
Text |
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dc.relation.essn |
1364-548X |
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dc.relation.issn |
1359-7345 |
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dc.relation.doi |
http://dx.doi.org/10.1039/C5CC06988B |
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dc.bibliographicCitation.issue |
96 |
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dc.bibliographicCitation.volume |
51 |
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dc.bibliographicCitation.date |
2015 |
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dc.bibliographicCitation.firstPage |
17088 |
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dc.bibliographicCitation.lastPage |
17091 |
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dc.description.version |
publishedVersion |
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tib.accessRights |
frei zug�nglich |
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