Zusammenfassung: |
Oxidative rearrangements are key reactions during the biosyntheses of many secondary metabolites in fungi. This review highlights the most important examples of these reactions and aims to draw together key mechanistic themes to allow a better understanding and future exploitation of this key class of fungal catalysts.
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Lizenzbestimmungen: |
CC BY-NC 3.0 Unported - http://creativecommons.org/licenses/by-nc/3.0/
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Publikationstyp: |
Article |
Publikationsstatus: |
publishedVersion |
Erstveröffentlichung: |
2014-07-25 |
Schlagwörter (deutsch): |
Cephalosporine, Cephalosporine C, Biosynthese, Cephalosporine C-Biosynthese, Kernmagnetische Resonanz, Kernspinresonanz, zellfreier Extrakt, Rohextrakt, Aflatoxin, Aflatoxin-Biosynthese, Ringerweiterung, Aspergillus nidulans, Gießkannenschimmel, Penicillin N, Desacetoxycephalosporin C, Heterologe Expression, Polyketid, Polyketid-Biosynthese
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Schlagwörter (englisch): |
cephalosporin-c biosynthesis, nuclear-magnetic-resonance, cell-free-extracts, aflatoxin biosynthesis, ring-expansion, aspergillus-nidulans, penicillin-n, deacetoxycephalosporin-c, heterologous expression, polyketide biosynthesis
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Fachliche Zuordnung (DDC): |
540 | Chemie, 570 | Biowissenschaften, Biologie
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Kontrollierte Schlagwörter: |
Cephalosporin C, Biosynthese, Magnetische Kernresonanz, Extrakt, Aflatoxin, Ringerweiterung <Chemie>, Aspergillus nidulans, Penicilline, Heterologe Genexpression
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