Spin state switching of metal complexes by visible light or hard X-rays

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Unruh, Daniel; Homenya, Patrick; Kumar, Manish; Sindelar, Ralf; Garcia, Yann et al.: Spin state switching of metal complexes by visible light or hard X-rays. In: Dalton Transactions 45 (2016), Nr. 36, S. 14008-14018. DOI: http://dx.doi.org/10.1039/C6DT01745B

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Sum total of downloads: 361




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Abstract: 
Electromagnetic stimuli of spin crossover compounds restricted to UV-vis light irradiation for many years could be recently extended to X-ray excitation. This review covers a large variety of light-induced effects, as well as recent analogues stimulated by X-ray irradiation which have not yet been reviewed. The focus is also on multistable multinuclear spin crossover compounds which are the subject of lively discussions within the spin crossover community. Their spin transition often occurs incompletely and with different switching mechanisms. In this review, we recall a predicted sequential switching induced thermally as well as a concerted stimulation mechanism by light irradiation for these interesting multifunctional materials.
License of this version: Es gilt deutsches Urheberrecht. Das Dokument darf zum eigenen Gebrauch kostenfrei genutzt, aber nicht im Internet bereitgestellt oder an Außenstehende weitergegeben werden. Dieser Beitrag ist aufgrund einer (DFG-geförderten) Allianz- bzw. Nationallizenz frei zugänglich.
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2016
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Germany Germany 264 73.13%
2 image of flag of United States United States 28 7.76%
3 image of flag of China China 12 3.32%
4 image of flag of Korea, Republic of Korea, Republic of 7 1.94%
5 image of flag of France France 5 1.39%
6 image of flag of No geo information available No geo information available 4 1.11%
7 image of flag of Russian Federation Russian Federation 4 1.11%
8 image of flag of Japan Japan 4 1.11%
9 image of flag of Romania Romania 3 0.83%
10 image of flag of Indonesia Indonesia 3 0.83%
    other countries 27 7.48%

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