Scale-up of the electrodeposition of ZnO/Eosin Y hybrid thin films for the fabrication of flexible dye-sensitized solar cell modules

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Bittner, F.; Oekermann, T.; Wark, M.: Scale-up of the electrodeposition of ZnO/Eosin Y hybrid thin films for the fabrication of flexible dye-sensitized solar cell modules. In: Materials 11 (2018), Nr. 2, 232. DOI: https://doi.org/10.3390/ma11020232

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Abstract: 
The low-temperature fabrication of flexible ZnO photo-anodes for dye-sensitized solar cells (DSSCs) by templated electrochemical deposition of films was performed in an enlarged and technical simplified deposition setup to demonstrate the feasibility of the scale-up of the deposition process. After extraction of eosin Y (EY) from the initially deposited ZnO/EY hybrid films, mesoporous ZnO films with an area of about 40 cm2 were reproducibly obtained on fluorine doped tin oxide (FTO)-glass as well as flexible indium tin oxide (ITO)-polyethylenterephthalate (PET) substrates. With a film thickness of up to 9 μm and a high specific surface area of up to about 77 m2·cm-3 the ZnO films on the flexible substrates show suitable properties for DSSCs. Operative flexible DSSC modules proved the suitability of the ZnO films for use as DSSC photo-anodes. Under a low light intensity of about 0.007 sun these modules achieved decent performance parameters with conversion efficiencies of up to 2.58%. With rising light intensity the performance parameters deteriorated, leading to conversion efficiencies below 1% at light intensities above 0.5 sun. The poor performance of the modules under high light intensities can be attributed to their high series resistances. © 2018 by the authors.
License of this version: CC BY 4.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2018
Appears in Collections:Naturwissenschaftliche Fakultät

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pos. country downloads
total perc.
1 image of flag of Germany Germany 137 63.72%
2 image of flag of United States United States 26 12.09%
3 image of flag of China China 20 9.30%
4 image of flag of No geo information available No geo information available 4 1.86%
5 image of flag of Vietnam Vietnam 3 1.40%
6 image of flag of Romania Romania 2 0.93%
7 image of flag of Myanmar Myanmar 2 0.93%
8 image of flag of Morocco Morocco 2 0.93%
9 image of flag of Czech Republic Czech Republic 2 0.93%
10 image of flag of Austria Austria 2 0.93%
    other countries 15 6.98%

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