Comparison of the thermal stability of single Al2O3 layers and Al2O3/SiNx stacks for the surface passiviation of silicon

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Veith, B.; Werner, F.; Zielke, D.; Brendel, Rolf; Schmidt, Jan: Comparison of the thermal stability of single Al2O3 layers and Al2O3/SiNx stacks for the surface passiviation of silicon. In: Energy Procedia 8 (2011), S. 307-312. DOI: https://doi.org/10.1016/j.egypro.2011.06.141

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Abstract: 
We measure surface recombination velocities (SRVs) below 10 cm/s on low-resistivity (1.4 Ωcm) p-type crystalline silicon wafers passivated with plasma-assisted and thermal atomic layer deposited (ALD) aluminium oxide (Al2O3) films. Ultrathin Al2O3 films (< 5 nm) are particularly relevant for the implementation into solar cells, as the deposition rate of the ALD process is very low compared to e.g. plasma-enhanced chemical vapor deposition (PECVD). Hence, we examine the passivation quality of a stack consisting of an ultrathin Al2O 3 passivation layer deposited by ALD and a SiNx capping layer deposited by PECVD. Our experiments show a substantial improvement of the thermal stability during firing at 810°C for the Al2O 3/SiNx stacks compared to a single Al2O 3 layer. We report on a 'regeneration effect' observed for Al 2O3 single layers after firing, where the degraded passivation is significantly improved after annealing at 400°C and also by illumination at room temperature using a halogen lamp. Nevertheless, for Al 2O3/SiNx stacks we measure SRVs < 15 cm/s after firing, whereas for Al2O3 single layers the regenerated SRVs are in the range of 10-30 cm/s. Al2O 3/SiNx stacks are hence ideally suited for the implementation into industrial-type silicon solar cells, although 'regenerated' Al2O3 single layers should result in a comparable cell performance.
License of this version: CC BY-NC-ND 3.0 Unported
Document Type: Article
Publishing status: publishedVersion
Issue Date: 2011
Appears in Collections:Fakultät für Mathematik und Physik

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1 image of flag of Germany Germany 206 50.74%
2 image of flag of United States United States 72 17.73%
3 image of flag of China China 29 7.14%
4 image of flag of Korea, Republic of Korea, Republic of 13 3.20%
5 image of flag of Netherlands Netherlands 9 2.22%
6 image of flag of France France 9 2.22%
7 image of flag of No geo information available No geo information available 7 1.72%
8 image of flag of Mexico Mexico 7 1.72%
9 image of flag of India India 5 1.23%
10 image of flag of Spain Spain 5 1.23%
    other countries 44 10.84%

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